Product name: |
1,1,1,3,3,3-Hexamethyldisilazane |
CAS RN: |
999-97-3 |
SAFETY DATA SHEET: |
1、HAZARDS IDENTIFICATION |
Classification of the substance or mixture |
PHYSICAL HAZARDS |
Flammable liquids Category 2
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HEALTH HAZARDS |
Acute toxicity (Oral) Category 4
Acute toxicity (Dermal) Category 3
Acute toxicity (Inhalation) Category 3
Skin corrosion/irritation Category 1B
Serious eye damage/eye irritation Category 1
Specific target organ toxicity - Single exposure [Category 1]
Nervous system Specific target organ toxicity - Single exposure [Category 3]
Respiratory tract irritation, Narcotic effects
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ENVIRONMENTAL HAZARDS |
Acute aquatic hazard Category 3
Long-term aquatic hazard Category 3
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Label elements |
Pictograms or hazard symbols |
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Signal word |
Danger |
Hazard statements |
Highly flammable liquid and vapour
Harmful if swallowed
Toxic in contact with skin or if inhaled
Causes severe skin burns and eye damage
Causes damage to organs : Nervous system
May cause respiratory irritation
May cause drowsiness or dizziness
Harmful to aquatic life
Harmful to aquatic life with long lasting effects
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Precautionary statements
[Prevention] |
Keep away from heat, sparks, open flames and hot surfaces. -No smoking.
Keep container tightly closed.
Ground and bond container and receiving equipment.
Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
Do not breathe mist, vapors or spray.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Do not eat, drink or smoke when using this product.
Wash hands and face thoroughly after handling.
Wear protective gloves, protective clothing, face protection.
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[Response] |
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. If exposed or concerned: Call a POISON CENTER or doctor. In case of fire: Use dry chemical, dry sand or foam to extinguish.
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[Storage] |
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
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[Disposal] |
Dispose of contents and container in accordance with local, regional, national regulations. |
2、COMPOSITION/INFORMATION ON INGREDIENTS |
Substance/mixture: Substance
Components: 1,1,1,3,3,3-Hexamethyldisilazane
Percent: >96.0%(GC)
CAS RN: 999-97-3
Synonyms: HMDS
Chemical Formula: C6H19NSi2
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3、 PHYSICAL AND CHEMICAL PROPERTIES |
Physical state (20°C): Liquid
Form: Clear
Colour: Colorless - Almost colorless
Odour: Ammoniacal
pH: No data available
Melting point/freezing point: No data available
Boiling point/range: 126°C Flash point: 8°C
Flammability or explosive limits:
Lower: 0.8%
Upper: 16.3%
Vapour pressure: 1.8kPa/25°C
Relative density: 0.77 Solubility(ies):
[Water] No data available
[Other solvents] Miscible: Ether, Benzene
Log Pow: 2.62
Autoignition temperature: 380°C
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4、STABILITY AND REACTIVITY |
Chemical stability: Stable under proper conditions.
Possibility of hazardous reactions: No special reactivity has been reported.
Conditions to avoid: Spark, Open flame, Static discharge Incompatible materials: Oxidizing agents, Strong acids
Hazardous decomposition products: Carbon monoxide, carbon dioxide etc
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